Ni(II) and Co(II) acetato complexes of pyrazole-pyridine based ligand: synthesis, structure and thermal decomposition
- Received: January, 25, 2023
- Revised: April, 17, 2023
- Accepted for publication: April, 17, 2023
- DOI 10.26902/JSC_id111520
- EDN: SMTIQU
- Views: 197
Department of Chemistry, Faculty of Science and Literature, Balikesir University, Balikesir, Turkey
Two novel acetato complexes with NNN type planar bdmpp ligand, [Ni(OAc)(H2O)2(bdmpp)]OAc (1) and [Co(OAc)(H2O)2(bdmpp)]OAc (2) (bdmpp: 2,6-bis(3,5-dimethylpyrazolyl)pyridine) were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction analysis. Thermal stabilities of these complexes were studied by thermogravimetric and differential thermal analyses. The crystal structures of both complexes were also determined using single-crystal X-ray diffraction. It was found that complexes 1 and 2 possessed smilar octahedral coordination
environment in which metal ions were coordinated by N donor atoms of bdmpp, two
oxygens of aqua ligands and one oxygen atom from terminal bonding acetato
ligand.
Keywords: acetato complexes, pyrazole-pyridine ligand, nickel(II), cobalt(II), single crystal, FTIR spectroscopy, thermogravimetry, crystal structure
|
Импакт-фактор 2024 1.4 |
||||
|
Срок опубликования 4 мес |
||||
Уважаемые авторы и подписчики “Журнала структурной химии”,
в свободном доступе
архив ЖСХ до 2021 года ("Номера").
Спецвыпуски
Самое интересное
Статьи, к которым чаще всего обращаются посетители
Рубрики