Tuning the dimensionality of H-bonded networks using different chalcogen atoms in [Re₆Q₈(CN)₆]^4– (Q = S, Se) clusters

ЖСХ, т.65, №5, 2024, 126941

Received: December, 18, 2023
Revised: January, 12, 2024
Accepted for publication: January, 19, 2024
DOI 10.26902/JSC_id126941
EDN: IUNAGN
Views: 169

¹ Институт неорганической химии им. А.В. Николаева СО РАН, Новосибирск, Россия

² Université de Strasbourg-CNRS, Strasbourg, France

Two novel compounds based on [Re₆Q₈(CN)₆]^4– (Q = S, Se) and small H-bond donor bis-amidinium dication of 2,2'-methylenediimidazolium (Cat) (Cat)₂[Re₆S₈(CN)₆]·2H₂O (1) and (Cat)₂[Re₆Se₈(CN)₆]·2H₂O (2) are synthesized and structurally characterized. the dimensionality (2D and 3D) of the obtained network and the nature of the H-bond pattern change depending on the chalcogen atom (S or Se) in the cluster anion.

Keywords: rhenium cluster, dications, H bonds, amidinium, charge-assisted hydrogen bonding

Импакт-фактор 2023 1.2
Срок опубликования 4 мес

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Tuning the dimensionality of H-bonded networks using different chalcogen atoms in [Re₆Q₈(CN)₆]^4– (Q = S, Se) clusters