- Received: December, 18, 2023
- Revised: January, 12, 2024
- Accepted for publication: January, 19, 2024
- DOI 10.26902/JSC_id126941
- EDN: IUNAGN
- Views: 156
©
Леднева А.Ю.
1 , Наумов Н.Г.
1, Kyritsakas N.
2, Ferlay S.
2
1 Институт неорганической химии им. А.В. Николаева СО РАН, Новосибирск, Россия
2 Université de Strasbourg-CNRS, Strasbourg, France
Two novel compounds based on [Re6Q8(CN)6]4–
(Q = S, Se) and small H-bond donor bis-amidinium dication of 2,2'-methylenediimidazolium (Cat) (Cat)2[Re6S8(CN)6]·2H2O (1) and (Cat)2[Re6Se8(CN)6]·2H2O (2) are synthesized
and structurally characterized. the
dimensionality (2D and 3D) of the obtained network and the nature of the H-bond
pattern change depending on the chalcogen atom (S or Se) in the cluster anion.
Keywords: rhenium cluster, dications, H bonds, amidinium, charge-assisted hydrogen bonding